Showing 6 results for Absorption
Fathi Brioua, Chouaib Daoudi,
Volume 21, Issue 2 (6-2024)
Abstract
We have modeled theoretical incident photon-to-current electricity (IPCE) action spectra of poly(3-hexylthiophene) (P3HT) and [6,6]-Phenyl C61 butyric acid methyl ester active layer bulk-heterojunction. By the two-dimensional optical model of a multilayer system based on the structure of Glass substrate / SiO2 /ITO/ PEDOT: PSS /P3HT: PCBM(1:1)/Ca/Al, the optical responses of the device have been computed for different photoactive layer and Ca layer thicknesses to found an optimal structure which allows obtaining the maximum absorption localized in the active layer and high device performance. The electric field intensity, energy dissipation, generation rate, and IPCE have been computed to enhance the device's performance. The finite element method executes the simulation under an incident intensity of 100 mW/cm2 of the 1.5 AM illumination. It was found that the optimum structure is achieved by a 180 nm photoactive layer and 5 nm Ca layer thicknesses.
Raghad Hadi, Furqan Almyahi,
Volume 21, Issue 4 (12-2024)
Abstract
In this investigation, a formulation was developed as a solution and thin films by combining poly (3-hexylthiophene) (P3HT) and fullerene Indene-C60 multi-adducts (ICxA) with varying solvent ratios. The formulations were prepared under ambient conditions. Morphological parameters were assessed utilizing a transmission electron microscope, scanning electron microscope and complemented by optical microscope pictures. UV-Visible absorbance and photoluminescence (PL) measurements were implemented to investigate the optical properties of active layers The values of the energy gaps of the prepared thin films and solutions increased as the solvent ratios of chlorobenzene to stander solvent increased, as a result of the isolation of P3HT chains from their neighbours. The Raman spectra are associated with high aggregation of composition and increased conformation when the intensity ratio (IC= C/IC-C) is small and the full width at high maximum (FWHM) is low. In ambient conditions, organic photovoltaic cells (OPVs) are produced with varying solvent ratios. The device with a 30% ratio exhibited the highest performance, with a power conversion efficiency (PCE) of approximately 1%, an open circuit voltage (VOC) of 0.571 V, a short circuit current density (JSC) of 7.47 mA.cm-2, and a fill factor (FF) of 38.6%.
Noor Alhuda Hassan, Zainab Jaf, Hanaa Ibrahem, Mohammed Hamid, Hussein Miran,
Volume 22, Issue 2 (6-2025)
Abstract
This work reports the influence of Cu dopant and annealing temperature on CdOx thin films deposited on glass substrates by spray-pyrolysis method. The Cu doping concentrations were 0, 0.46, and 1.51 at% with respect to the CdOx undoped material. Then, the fabricated films were subjected to annealing process at temperature of 450°C. X-ray diffraction (XRD) examination confirms that the as-deposited films show a cubic crystallographic structure with high purity of CdO in the annealed films. It was found that the (111) peak is the most predominant diffraction orientation in the surveyed samples. At the microscopic scale, AFM machine was operated to quantify the three important parameters of the mean roughness (Ra), rms value (Rq), and z scale. These parameters hold highest values for the sample with 0.46 at% of Cu. Finally, reflectance, absorbance, transmittance and other optical parameters dielectric measurements were comprehensively analyzed. Our evaluation of optical band gaps for the studied samples reveals that the synthesized films have direct band gap character with the fact that the rise in the Cu contents in the as-deposited films lead to lessen the band gap values. In contrast, annealing process results in raising the band gap.
